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The strainless theory for the stability of cyclic compounds refers to the concept that cyclic compounds are thermodynamically more stable than acyclic compounds with the same molecular formula, due to the reduction of ring strain in cyclic compounds. Ring strain is defined as the difference in energy between a molecule in its ideal geometry and its actual geometry. The strainless theory states that cyclic compounds have a lower ring strain than acyclic compounds due to the ability of the cyclic structure to distribute the bond angles more evenly around the ring, reducing the energy difference. This results in a thermodynamic advantage and higher stability for cyclic compounds compared to their acyclic counterparts.

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